Product ID:AUTO DIESEL, 31100
MSDS Date:11/03/1988
FSC:9150
NIIN:00N026209
MSDS Number: BMRNB

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: J.C. WILLETT

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

HIPS TO PVNT ASPIR OF LIQ IN LUNGS.GET MD. NOTE TO

RTECS: 9999999ZZ

HAS NOT OCCURED. EMESIS SHOULD BE INDUCED

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IF SYMP SUCH AS LOSS OF GAG REFLEX, CONVULS/UNCON

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ENDOTRACHEAL TUBE SHOULD BE CONSIDERED.

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SUCH AS CLAY, SAND/OTHER SUITABLE MATL; PLACE IN

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FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE; DISPOSE

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IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL.

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USE (ONLY) WITH ADEQ VENT. CNTNRS, EVEN THOSE

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CUT, DRILL, GRIND, WELD/PERFORM SIMILAR OPER ON/NEAR

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DIESEL FUELS; (SHELL AUTO DIESEL)

CAS: 68334-30-5

RTECS: HZ1800000

Fraction By Weight: 100%

PRESS USAGE MAY RESULT IN INJECTION OF OIL IN SKIN

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TO UPPER RESP TRACT. HIGH CONC MAY RESULT IN CNS

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MAY RESULT IN VOMIT; ASPIR OF VOMIT IN

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ASPIR PNEUM. RPTD DERMAL APPLICATN OF HIGH LEVS OF

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PRODUCED EXTREMELY SEVERE IRRIT TO CORR ACTION ON

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IN THESE STUDIES, INCL CONGESTION, ENLARGEMENT,

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BE EVIDENCED BY COUGHING, LABORED

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DO NOT INDUCE

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:BASED ON ESSENTIALLY SIMILAR PROD
TESTING,LIQ IS PRACTICALLY NONIRRIT. SKIN:BASED ON ESSENTIALLY
SIMILAR PROD TESTING, LIQ IS PRESUMED TO BE MODERATELY IRRIT.
PRLNGD/RPTD LIQ CONT CAN RESULT IN DE FAT & DRYING OF SKIN WHICH
MAY RESULT IN SEVERE IRRIT & DERMAT. MAY CAUSE MILD SKIN SENSIT.
RELS DURING HIGH (ING 2)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:IRRIT AS NOTED. SKIN SENSIT (ALLERGY) MAY BE
EVIDENCED BY RASHES, ESP HIVES. EARLY TO MODERATE CNS DEPRESS MAY
BE EVIDENCED BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON &
DEATH MAY OCCUR. LOC N ECROSIS IS EVIDENCED BY DELAYED ONSET OF
PAIN & TISS DMG A FEW HRS FOLLOWING INJECTION. ASPIR PNEUM MAY (ING
8)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN & RESP DISORDERS
MAY BE AGGRAVATED BY EXPOS. PREEXISTING SKIN/LUNG ALLERGIES MAY
INCR CHANCE OF DEVELOPING INCREASED ALLERGY SYMP FROM EXPOSURE TO
PRODUCT.

First Aid:EYE:FLUSH WITH WATER FOR AT LEAST 15 MIN. IF IRRIT OCCURS,
GET MD. SKIN:REMOVE CONTAM CLTHG/SHOES & WIPE EXCESS FROM SKIN.
FLUSH WITH WATER. FOLLOW BY WASHING W/SOAP & WATER. IF IRRIT
OCCURS, GET MD. DO NOT REUSE CLTHG UNTIL CLEANED. IF MATL IS
INJECTED UNDER SKIN, GET MD IMMED TO PVNT SERIOUS DMG; DO NOT WAIT
FOR SYMP TO DEVELOP. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE
OXYGEN IF (ING 9)

Flash Point Method:PMCC
Flash Point:130F,54C
Extinguishing Media:USE WATER FOG/FOAM, DRY CHEM/CO*2.DO NOT USE DIRECT
STREAM OF WATER.PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.CAUTION.COMBUST.COOL FIRE EXPSD CNTNRS W/WATER.IN CASE OF LRG
FIRES, ALSO COOL SURROUNDING EQUIP(SUPP DATA)
Unusual Fire/Explosion Hazard:CNTNRS EXPSD TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS BUILDUP WHICH COULD
RESULT IN CNTNR RUPTURE.CNTNR AREAS EXPSD TO (SUPP DATA)

Spill Release Procedures:LRG SPILLS: ELIM POTENTIAL SOURCES OF
IGNIT.WEAR APPROP NIOSH/MSHA APPRVD RESP & OTHER PROT CLTHG.SHUT
OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO.DIKE & CONTAIN.REMOVE
W/VACUUM TRUCKS/PUMP TO STORAGE/SA LVAGE VESSELS.SOAK UP RESIDUE
W/AN ABSORB(ING 14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP LIQ & VAP AWAY FROM HEAT, SPARKS
& FLAME. SURF THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQ PROD IN
ABSENCE OF SPARKS/FLAME.
Other Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN OFF OTHER
SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE. VAPS MAY
ACCUM & TRAVEL TO IGNIT SOURCES DISTANT FROM HNDLG SITE; FLASH-FIRE
CAN RESULT. KEEP CNTNRS CLSD WHEN NOT IN USE.(ING 17)

Respiratory Protection:USE A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. IN ACCORDANCE WITH 29 CFR 1910.134, USE EITHER A
NIOSH/MSHA APPROVED FULL-FACE, ATMOSPHERE-SUPPLYING RESP OR A
NIOSH/MSHA APPROVED AIR-PUR IFYING RESP FOR ORG VAPS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING TO MINIMIZE CONTACT.
Work Hygienic Practices:WASH WITH SOAP & WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE
REUSE.
Supplemental Safety and Health
FIRE FIGHT PROC:& STRUCTURES WITH WATER. EXPLO HAZ:DIRECT FLAME CONT
SHOULD BE COOLED W/LRG QTYS OF WATER AS NEEDED TO PVNT WEAKENING OF
CNTNR STRUCTURE. HAZ DECOMP PRODS:& GASES WILL EVOLVE WHEN THIS
MATL UNDERGOES PYROLYSIS/COMBUST. CO &OTHER UNIDENTIFIED ORG CMPDS
MAY BE FORMED UPON COMBUST.

HCC:F4
Boiling Pt:B.P. Text:325F,163C
Vapor Density:>1
Spec Gravity:0.8762
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOW LIQUID; STRONG HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, FLAME.
Hazardous Decomposition Products:THERM DECOMP PRODS ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. COMPLEX MIXT OF AIRBORNE SOLID, LIQ,
PARTICULATES(SUPP DATA)

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.